Synthesis of Biodiesel in Batch and Packed-Bed Reactors Using Powdered and Granular Sugar Catalyst

29th Symposium of Malaysian Chemical Engineers 2016

Janaun, J.^1,2 ; Lim, P.M.^1 ; Balan, W.S.^1 ; Yaser, A.Z.^1 ; Chong, K.P.^2

Chemical Engineering Programme, Faculty of Engineering, Universiti Malaysia Sabah, Jalan UMS, Sabah Malaysia, Kota Kinabalu

88400, Malaysia^1

Sustainable Palm Oil Research Unit (SPOR), Faculty of Sustainable Agriculture, Universiti Malaysia Sabah, Jalan UMS, Sabah Malaysia, Kota Kinabalu

88400, Malaysia^2

关键词: Biodiesel production;    Continuous reactions;    Esterification reactions;    Experimental conditions;    Functionalizations;    Packed bed reactor;    Physical and chemical properties;    Renewable energies;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/206/1/012015/pdf
DOI  :  10.1088/1757-899X/206/1/012015

来源: IOP

【 摘 要 】

Increasing world production of palm oil warrants effective utilization of its waste. In particular, conversion of waste cooking oil into biodiesel has obtained global interest because of renewable energy need and reduction of CO2emission. In this study, oleic acid used as a model compound for waste cooking oil conversion using esterification reaction catalysed by sugar catalyst (SC) in powdered (P-SC) and granular (G-SC) forms. The catalysts were synthesized via incomplete carbonization of D-glucose followed by functionalization with concentrated sulphuric acid. Catalysts characterizations were done for their physical and chemical properties using modern tools. Batch and packed-bed reactor systems were used to evaluate the reactivity of the catalysts. The results showed that G-SC had slightly higher total acidity and more porous than P-SC. The experimental conditions for batch reaction were temperature of 60°C, molar ratio of 1:20 (Oleic Acid:Methanol) and 2 wt. catalyst with respect to oleic acid. The results showed the maximum oleic acid conversion using G-SC and P-SC were 52 and 48, respectively. Whereas, the continuous reaction with varying feed flow rate as a function of retention time was studied by using 3 g of P-SC in 60 °C and 1:20 molar ratio in a packed-bed reactor. The results showed that a longer retention time which was 6.48 min and feed flow rate 1.38 ml/min, achieved higher average conversion of 9.9 and decreased with further increasing flow rate. G-SC showed a better average conversion of 10.8 at lowest feed flow rate of 1.38 ml/min in continuous reaction experiments. In a broader perspective, large scale continuous biodiesel production is feasible using granular over powdered catalyst mainly due to it lower pressure drop.