Pin-Hole Free Perovskite Film for Solar Cells Application Prepared by Controlled Two-Step Spin-Coating Method

3rd International Conference on Functional Materials Science 2016

Bahtiar, A.^1 ; Rahmanita, S.^1 ; Inayatie, Y.D.^1

Department of Physics, Universitas Padjadjaran, Jl. Raya Bandung-Sumedang km. 21, Jatinangor, Sumedang

45363, Indonesia^1

关键词: Coating parameters;    Current voltage curve;    Hole transport materials;    Morphological properties;    Perovskite crystal;    Series resistances;    Spin coating process;    Spin-coating method;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/196/1/012037/pdf
DOI  :  10.1088/1757-899X/196/1/012037

来源: IOP

【 摘 要 】

Morphology of perovskite film is a key important for achieving high performance perovskite solar cells. Perovskite films are commonly prepared by two-step spin-coating method. However, pin-holes are frequently formed in perovskite films due to incomplete conversion of lead-iodide (PbI2) into perovskite CH3NH3PbI3. Pin-holes in perovskite film cause large hysteresis in current-voltage curve of solar cells due to large series resistance between perovskite layer-hole transport material. Moreover, crystal structure and grain size of perovskite crystal are also other important parameters for achieving high performance solar cells, which are significantly affected by preparation of perovskite film. We studied the effect of preparation of perovskite film using controlled spin-coating parameters on crystal structure and morphological properties of perovskite film. We used two-step spin-coating method for preparation of perovskite film with varied spinning speed, spinning time and temperature of spin-coating process to control growth of perovskite crystal aimed to produce high quality perovskite crystal with pin-hole free and large grain size. All experiment was performed in air with high humidity (larger than 80%). The best crystal structure, pin-hole free with large grain crystal size of perovskite film was obtained from film prepared at room temperature with spinning speed 1000 rpm for 20 seconds and annealed at 100°C for 300 seconds.