Cryomilled and spark plasma sintered titanium: the evolution of microstructure

7th International Conference on Nanomaterials by Severe Plastic Deformation

Kozlík, Jií^1 ; Becker, Hanka^2 ; Harcuba, Petr^1 ; Stráský, Josef^1 ; Janeek, Milos^1

Department of Physics of Materials, Charles University, Prague, Czech Republic^1

Institute of Materials Science, TU Bergakademie Freiberg, Freiberg, Germany^2

关键词: Field assisted sintering techniques;    Lower sintering temperatures;    Processing parameters;    Severe plastic deformations;    Sintering temperatures;    Trade-off relationship;    Ultra fine grained microstructure;    Ultra-fine grained ( UFG);   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/194/1/012023/pdf
DOI  :  10.1088/1757-899X/194/1/012023

来源: IOP

【 摘 要 】

Bulk ultra-fine grained (UFG) commercially pure Ti was prepared by cryogenic milling in liquid argon and subsequent spark plasma sintering (SPS). During cryogenic milling, individual powder particles are repetitively severely deformed by attrition forces. Powder particles were not significantly refined, but due to severe repetitive plastic deformation, ultra-fine grained microstructure emerges within each powder particle. Cryogenic milling can be therefore considered as a specific severe plastic deformation (SPD) method. Compactization of cryomilled powder by SPS technique (also referred to as field assisted sintering technique - FAST) requires significantly lower sintering temperatures and shorter sintering times for successful compaction when compared to any other sintering technique. This is crucial for maintaining the UFG microstructure due to its limited thermal stability. Several specimens were prepared by varying processing parameters, in particular the sintering temperature. The microstructure of powders and compacted samples was observed by scanning electron microscopy (SEM). Increased sintering temperature results in recrystallization and grain growth. A trade-off relationship between the density of compacted material and grain size was identified. Microhardness of the material was found to depend on residual porosity rather than grain size. This contribution presents cryogenic milling and spark plasma sintering as a viable alternative for achieving UFG microstructure in commercially pure Ti.