Superabsorbent nanocomposite synthesis of cellulose from rice husk grafted poly(acrylate acid-co-acrylamide)/bentonite

International Symposium on Current Progress in Functional Materials

Helmiyati^1 ; Abbas, G.H.^1 ; Kurniawan, S.^1

Department of Chemistry, Faculty of Mathematics, Natural Sciences Universitas Indonesia, Kampus UI Depok, Depok

16424, Indonesia^1

关键词: Acrylamide monomers;    Cross linking agents;    Methylene bisacrylamide;    Nanocomposite synthesis;    Nanocrystal structures;    Potassium persulfate;    Rice husk;    Swelling capacities;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/188/1/012024/pdf
DOI  :  10.1088/1757-899X/188/1/012024

来源: IOP

【 摘 要 】

Superabsorbent nanocomposite synthesis of cellulose rice husk as the backbone with free radical polymerization method in copolymerization grafted with acrylic acid and acrylamide monomer. The cellulose was isolated from rice husk with mixture of toluene and ethanol and then hemicellulose and lignin were removed by using potassium hydroxide 4% and hydrogen peroxide 2%. The obtained cellulose rendement was 37.85%. The functional group of lignin analyzed by FTIR spectra was disappeared at wavenumber 1724 cm-1. Crystal size of the obtained isolated cellulose analyzed by XRD diffraction pattern was 34.6 nm, indicated the nanocrystal structure. Copolymerization was performed at temperature of 70°C with flow nitrogen gas. Initiator and crosslinking agent used were potassium persulfate and N′N-methylene-bis-acrylamide. The swelling capacity of water and urea showed the results was quite satisfactory, the maximum swelling capacity in urea and water were 611.700 g/g and 451.303 g/g, respectively, and can be applied in agriculture to absorb water and urea fertilizer.