Improve sonocatalytic performance using modified semiconductor catalyst SnO2 and ZrO2 by magnetite materials

International Symposium on Current Progress in Functional Materials

Paramarta, V.^1,2 ; Kristianto, Y.^1,2 ; Taufik, A.^1,2 ; Saleh, R.^1,2

Department of Physics, Faculty of Mathematics, Natural Sciences Universitas Indonesia, Kampus UI Depok, Depok

16424, Indonesia^1

Integrated Laboratory of Energy and Environment, Faculty of Mathematics, Natural Sciences Universitas Indonesia, Kampus UI Depok, Depok

16424, Indonesia^2

关键词: Catalytic performance;    Cubic spinel structure;    Degradation efficiency;    Ferromagnetic behaviors;    Semiconductor catalysts;    Separation efficiency;    Ultrasonic radiation;    Vibrating sample magnetometer;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/188/1/012042/pdf
DOI  :  10.1088/1757-899X/188/1/012042

来源: IOP

【 摘 要 】

Modifying semiconductor catalysts using magnetic materials could enhance the efficiency of wastewater removal and the separation efficiency demonstrated in our previous studies. The catalytic performance of wide band gap ZrO2and SnO2semiconductors has not been studied with regard to the ultrasonic radiation catalytic process. Therefore, the ultrasound-assisted sonocatalytic performance of ZrO2and SnO2semiconductors combined with Fe3O4(magnetite) nanoparticles has been studied using methylene blue as a model organic pollutant. The nanocomposites were synthesized using sol-gel methods. The structural properties of the samples were characterized using X-ray diffraction (XRD). Sample morphology was obtained by transmission electron microscopy (TEM). The magnetic properties of the samples were characterized using a vibrating sample magnetometer (VSM). The cubic spinel structure of Fe3O4is successfully identified, as are the tetragonal structures from SnO2and ZrO2. The samples exhibit ferromagnetic behavior at room temperature. Both ZrO2and SnO2combined with Fe3O4show better sonocatalytic efficiency than without Fe3O4and even better efficiency than the pioneering wide band gap semiconductor TiO2. The combination of magnetite nanoparticles with SnO2exhibit the highest degradation efficiency. The incorporation of magnetic material into catalysts has been proved to enhance the reusability of catalysts with efficient separation process.