The Produce of Methyl Ester from Crude Palm Oil (CPO) Using Heterogene Catalyst Ash of Chicken Bone (CaO) using Ethanol as Solvent

1st Annual Applied Science and Engineering Conference

工业技术;自然科学

Sinaga, M.S.^1 ; Fauzi, R.^2 ; Turnip, J.R.^1

Department of Chemical Engineering, Faculty of Engineering, Universitas Sumatera Utara, North Sumatera, Medan

20155, Indonesia^1

Department of Electrical Engineering, Faculty of Engineering, Universitas Sumatera Utara, North Sumatera, Medan

20155, Indonesia^2

关键词: Chicken bones;    Crude palm oil;    Heterogeneous base catalyst;    Heterogeneous catalyst;    Increasing temperatures;    Reaction temperature;    Standard requirements;    Yield differences;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/180/1/012125/pdf
DOI  :  10.1088/1757-899X/180/1/012125

来源: IOP

【 摘 要 】

Methyl Ester (methyl ester) is generally made by trans esterification using heterogeneous base catalyst. To simplify the separation, the heterogeneous catalyst is used, such as CaO, which in this case was isolated from chicken bones made by softening chicken bones and do calcination process. Some other important variables other than the selection of the catalyst is the catalyst dosage, molar ratio of ethanol to the CPO and the reaction temperature. The best result from this observe is at the molar ratio of ethanol to the CPO is 17: 1, the reaction temperature is 70 ° C and 7% catalyst (w.t) with reaction time for 7 hours at 500 rpm as a constant variable, got 90,052 % purity, so that this result does not get the standard requirements of biodiesel, because of the purity of the biodiesel standard temporary must be achieve > 96.5 %. This study aims to produce methyl ester yield with the influence of the reaction temperature, percent of catalyst and molar ratio of ethanol and CPO. The most influential variable is the temperature of the reaction that gives a significant yield difference of methyl ester produced. It's been proven by the increasing temperature used will also significantly increase the yield of methyl ester.