Esterification Reaction of Glycerol and Palm Oil Oleic Acid Using Methyl Ester Sulfonate Acid Catalyst as Drilling Fluid Formulation

11th Joint Conference on Chemistry in Conjunction with the 4th Regional Biomaterials Scientific Meeting

材料科学;化学;生物科学

Sari, V.I.^1 ; Hambali, E.^2,3 ; Suryani, A.^2,3 ; Permadi, P.^4

Program Study of Agriculture Industrial Technology, Postgraduate School, IPB DarmagaSt, Campus IPB, Bogor

16680, Indonesia^1

Surfactant and Bioenergy Research Center, LPPM, IPB Pajajaran St, Campus IPB, Baranangsiang, Bogor

16153, Indonesia^2

Department of Agroindustrial Technology, Faculty of Agricultural Technology, Bogor Agricultural University, Indonesia^3

Program Study of Petroleum Engineering, ITB, Indonesia^4

关键词: Esterification reactions;    Glycerol esters;    Increasing temperatures;    Methyl ester sulfonates;    Processing time;    Research results;    Stirring speed;    Temperature range;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/172/1/012062/pdf
DOI  :  10.1088/1757-899X/172/1/012062

来源: IOP

【 摘 要 】

Esterification reaction between glycerol with palm oil oleic acid to produce glycerol ester and one of the utilization of glycerol esters is as ingredients of drilling fluids formula for oil drilling needs. The purpose of this research is to get the best conditions of the esterification process. The esterification reaction does with the reactants is glycerol with purity of 97.6%, palm oil oleic acid with the molar ratio is 1:1, Methyl Ester Sulfonate Acid (MESA) catalyst 0.5%, and stirring speed 400 rpm. The temperature range of 180°C to 240°C and the processing time between 120 to 180 minutes. The results showed that the best conditions of the esterification reaction at the temperature 240°C and time process are 180 minute. The increasing temperature resulted that the acid number decreases and causing the conversion increased. The maximum conversion is 99.24%, density 0.93 g/cm3, flash point 241°C, pour point -3°C, the boiling point of 244 °C, the acid value of 1.90 mg KOH/g sample, kinematic viscosity 31.51 cSt (40°C), surface tension 37.0526 dyne/cm and GCMS identification, glycerol ester at 22,256 retention time (minutes) and wide area 73.75 (%). From the research results obtained glycerol ester with characteristics suitable for drilling fluid formulations.