Conformer of the peroxynitrite ion formed under photolysis of crystalline alkali nitrates _ cis or trans?

7th International Conference Radiation-thermal Effects and Processes in Inorganic Materials

材料科学;物理学

Pak, V. Kh.^1 ; Anan'Ev, V.A.^1 ; Dyagileva, E.P.^2 ; Lyrshchikov, S. Yu.^3 ; Miklin, M.B.^1 ; Rezvova, M.A.^1

Kemerovo State University, Krasnaya Str. 6, Kemerovo

650043, Russia^1

Kemerovo State Medical Academy, Voroshilova Str. 22a, Kemerovo

650029, Russia^2

National Research Tomsk Polytechnic University, Energetic Institute, Lenina avenue 30, Tomsk

634050, Russia^3

关键词: Alkali nitrates;    Alkali solutions;    Co-crystallizations;    Crystalline powder;    Infrared reflectance spectra;    Peroxynitrites;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/168/1/012091/pdf
DOI  :  10.1088/1757-899X/168/1/012091

学科分类：材料科学（综合）

来源: IOP

【 摘 要 】

The optical and infrared reflectance spectra of the crystalline powders prepared by co-crystallization of caesium nitrate, nitrite, and peroxynitrite from alkali solution have been studied. We find that the trans conformer forms under photolysis of crystalline pure caesium nitrate. Under its dissolution the trans conformer transforms to the cis conformer.