Research on interfacial polymerization of pyrrole assist with Span80 system

2016 Global Conference on Polymer and Composite Materials

材料科学;化学

Yang, Q.H.^1 ; Tu, Z.Y.^1 ; Zhao, N.Y.^1

College of Materials Science and Engineering, Xi'An University of Science and Technology, Xi'an

710054, China^1

关键词: Electrochemical performance;    Fourier transform infrared;    Interfacial polymerization;    Polypyrrole (PPy);    Scan rates;    Specific capacitance;    Structure and morphology;    Vesicular structure;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/137/1/012070/pdf
DOI  :  10.1088/1757-899X/137/1/012070

学科分类：材料科学（综合）

来源: IOP

【 摘 要 】

With assistance of surfactants, self-assembled Polypyrrole (PPy) film was prepared via oil / water interfacial polymerization. The chemical structure and morphologies of the obtained samples have been characterized by Fourier transform infrared (FT-IR) and Scanning Electron Microscope (SEM), respectively. The electrochemical performance recorded on an electrochemical workstation, mainly includes cyclic voltammetry (CV) tests. The prepared PPy film has its own extremely vesicular structures from results and indicates by using different concentration surfactant Span80. The PPy film prepared 25 °C with 3.32 g/L Span80 (surpass its critical micelle concentration) as a surfactant possess a supernal specific capacitance of 368.18 F/g at a scan rate 50 mV/s in 1 M NaNO3aqueous solution at.