Synthesis of carbon nanoparticles from commercially available liquified petroleum gas

International Conference on Innovation in Engineering and Vocational Education

自然科学;教育

Nandiyanto, A.B.D.^1 ; Fadhlulloh, M.A.^1 ; Rahman, T.^1 ; Mudzakir, A.^1

Departemen Kimia, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudi no 229, Jawa Barat, Bandung

40154, Indonesia^1

关键词: Absorption peaks;    Carbon Nano-Particles;    Gas chromatography-mass spectrometries (GC-MS);    Hexagonal graphites;    Infrared spectrum;    Liquefied petroleum gas (LPG);    Natural graphite;    Sample analysis;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/128/1/012042/pdf
DOI  :  10.1088/1757-899X/128/1/012042

来源: IOP

【 摘 要 】

The aim of this study was to synthesize carbon nanoparticles (CNPs) from commercially available liquefied petroleum gas (LPG). In the research procedure, LPG was reacted with air to construct CNPs. To confirm the successful synthesis of CNPs, we conducted several sample analyses: Gas Chromatography-Mass Spectrometry (GC-MS), Transmission Electron Microscope (TEM), X-ray Diffraction (XRD), and Infrared Spectra (FTIR). We also varied LPG and oxygen mole ratios at 0.8; 2.4; 4.8; and 7.2. The GC-MS results indicated the composition of LPG was propane (58.90%), isobutane (18.35%), butane (22.26%), and butane, 2-methyl (0.48%). The TEM results showed that the particles were spheres with sizes of between 25 and 35 nm. The sizes of particles were controllable, depending on the mole ratio. The XRD results showed mole ratios of LPG and oxygen of 0.80 and 2.40 were natural graphite, whereas the mole ratios of 4.80 and 7.20 were hexagonal graphite. FT-IR results showed CNPs have absorption peaks at wave number (i) 752 (C-H bend sp2); (ii) 835 (C=C); (iii) 1274 (C-O-C vibration); (iv) 1400 and 1600 (C-C stretch aromatic); (v) 2800 (C-H sp2); (vi) 2900 (CH sp3); (vii) 3100 (C-H aromatic); and (viii) 3400 cm-1(O-H). From the FTIR analysis results, the sample contained allotrope graphite due to detection of peaks at 1400 and 1600 cm-1(C-C stretch aromatic) and 3100 cm-1(C-H aromatic).