Combined effect of pulse electron beam treatment and thin hydroxyapatite film on mechanical features of biodegradable AZ31 magnesium alloy

3rd International Youth Conference on Interdisciplinary Problems of Nanotechnology, Biomedicine and Nanotoxicology

物理学;医药卫生;生态环境科学

Surmeneva, M.A.^1 ; Tyurin, A.I.^2 ; Teresov, A.D.^3 ; Koval, N.N.^3 ; Pirozhkova, T.S.^2 ; Shuvarin, I.A.^2 ; Surmenev, R.A.^1,4

Department of Theoretical and Experimental Physics, Tomsk Polytechnic University, Lenina ave., 30, Tomsk

634050, Russia^1

NanoCenter Nanotechnology and Nanomaterials, G.R. Derzhavin Tambov State University, Internationalnaya st.,33, Tambov

392000, Russia^2

Institute of High-Current Electronics, Siberian Branch, Russian Academy of Sciences, 2/3, Akademichesky ave., Tomsk

634050, Russia^3

Fraunhofer Institute for Interfacial Engineering and Biotechnology IGB, Nobelstraße, 12, Stuttgart, Germany^4

关键词: AZ31 magnesium alloy;    Energy dispersive X ray spectroscopy;    Hydroxyapatite coating;    Hydroxyapatite films;    Nano-indentation hardness;    Pulsed electron beams;    Radio frequency magnetron sputtering;    rf-Magnetron sputtering;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/98/1/012030/pdf
DOI  :  10.1088/1757-899X/98/1/012030

来源: IOP

【 摘 要 】

The morphology, elemental, phase composition, nanohardness, and Young's modulus of the hydroxyapatite (HA) coating deposited via radio frequency (RF) magnetron sputtering onto the AZ31 surface were investigated by atomic force microscopy (AFM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and nanoindentationtechniques. The calcium phosphate (Ca/P) molar ratio of the HA coating deposited via RF-magnetron sputtering onto AZ31 substrates according to EDX was 1.57+0.03. The SEM experiments revealed significant differences in the morphology of the HA film deposited on untreated and treated with the pulsed electron beam (PEB) AZ31 substrate. Nanoindentation studies demonstrated significant differences in the mechanical responses of the HA film deposited on the initial and PEB-modified AZ31 substrates. The nanoindentation hardness and the Young's modulus of the HA film on the magnesium alloy modified using the PEB treatment were higher than that of the HA layer on the untreated substrate. Moreover, the HA film fabricated onto the PEB-treated surface was more resistant to plastic deformation than the same film on the untreated AZ31 surface.