Synthesis of ultra dispersed graphite_like structures doped with nitrogen in supersonic carbon plasma flow

20th International Conference for Students and Young Scientists: Modern Techniques and Technologies

工业技术;材料科学

Sivkov, A.^1 ; Pak, A.^1 ; Shanenkov, I.^1 ; Kolganova, J.^1 ; Shatrova, K.^1

Tomsk Polytechnic University, Tomsk, Russia^1

关键词: Bonding configurations;    Capacitive energy storage;    Carbon plasmas;    Energy parameters;    Graphite-like carbons;    Graphite-like structures;    Nitrogen atmospheres;    Nitrogen atom;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/66/1/012001/pdf
DOI  :  10.1088/1757-899X/66/1/012001

来源: IOP

【 摘 要 】

In this paper the synthesis of ultra dispersed graphite-like structures doped with nitrogen by using a magneto plasma accelerator is shown. The synthesis of such structures is realized during supersonic carbon plasma jet flowing into the chamber filled with the nitrogen atmosphere. Plasma jet is generated by coaxial magneto plasma accelerator (CMPA) based on graphite electrode system. The CMPA is supplied from the pulsed capacitive energy storage with the maximum value of stored energy of 360 kJ. Electrical and energy parameters of plasma flow are recorded during experiment. According to X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM) methods obtained particles with well seen triangle sectors are graphite-like carbon structures doped with nitrogen atoms. This is confirmed by X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy analyses in which carbon- nitrogen bonding configurations have been identified.