EXAFS spectra using synchrotron radiation of Cu (II) complexes

International Conference on Recent Trends in Physics 2016

Ninama, Samrath^1 ; Mishra, A.^2

Kasturbagram Rural Institute, Kasurbagranm Indore [MP]

452020, India^1

School of Physics, Vigyan Bhawan, Devi Ahilya University, Indore

452001, India^2

关键词: Copper complexes;    Data analysis methods;    Derivative method;    Energy dispersive;    Extended x-ray absorption fine structure spectrum;    Fourier transformations;    Metal-ligand bonds;    Synchrotron source;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/755/1/012045/pdf
DOI  :  10.1088/1742-6596/755/1/012045

来源: IOP

【 摘 要 】

EXAFS analysis of Cu (II) complex as a ligand of 2-methyl-3-[(bis-aniline(R) phenyl]- 3H-1, 5 benzodiazepine. Extended X-ray absorption fine structure (EXAFS) spectra have been recorded at the K-edge of Cu (II) using the energy dispersive EXAFS beam line at 2.5GeV Indus - 2 synchrotron source at RRCAT, Indore, India. A theoretical EXAFS data analysis is also carried out by Fourier analysis of experimental EXAFS data of the copper (II) complexes. This analysis includes details of the Fourier transform of the data and the extraction of metal-ligand bond length. Bond lengths determined from data analysis methods are compared with the bond lengths obtained from several other known techniques, namely, Levy's, Lytle's and Lytle, Sayers and Stern's (LSS) methods. These data have also been calibrated by derivative method and bond lengths have also been obtained from Fourier transformation method and the results have been compared with the each other. The EXAFS data have been analyzed using the computer software Athena.