Characterization of mono-ethylene-glycol based industrial polyurethanes samples by fast-neutron radiography and neutron tomography

6th European Conference on Neutron Scattering

Rogante, Massimo^1 ; Söllradl, Stefan^2

Rogante Engineering Office, Contrada San Michele n. 61, Civitanova Marche

62012, Italy^1

Forschungs-Neutronenquelle Heinz Maier-Leibnitz (FRM II), Lichtenbergstrasse, Garching

85747, Germany^2

关键词: Different densities;    Fast neutron radiographies;    Functional properties;    Material degradation;    Mechanical loading;    Mono ethylene glycols;    Particular condition;    Structural organization;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/746/1/012042/pdf
DOI  :  10.1088/1742-6596/746/1/012042

来源: IOP

【 摘 要 】

A complicated structural organization of polyurethanes may have a strong influence on the materials functional properties. Under particular conditions such as mechanical and thermal loading and aging, it leads to the material degradation, even in fresh-prepared bulk polymers and especially if defects are present in the material. Unwanted bubbles can be observed, which form during the expansion of the mixture during its chemical reaction and remain present in the final product. These macro-, micro- and nano-bubbles influence the material's performance. In this work, neutron radiography and tomography have been adopted to characterize at a macro-scale level the bulk of commercially available polyurethane samples, obtained from dissimilar- mixture ratios with different densities and branching levels as well as from different zones of the production mould. The characterisation allowed an estimation of the different dense materials-as they are used, e.g., in soles of shoes-as well as the invisible defects like pores and cracks, responsible for the materials fracture by mechanical loading. The obtained information are expected to be useful for various industrial sectors such as automotive and footwear industry. It will be completed by applying SANS, which has already proved to characterize the microstructure of the bulk-polymer with respect to nano-pores, micro-cracks and their arrangement in the polymer matrix.