Investigation of chemical effect on the absorption parameters for some selected indium complex at 59.54 keV photon energy

International Physics Conference at the Anatolian Peak 2016

Akman, F.^1 ; Akman, F.^2 ; Kaçal, M.R.^3 ; Turhan, M.F.^4 ; Akdemir, F.^2 ; Araz, A.^2 ; Durak, R.^2

Bingöl University, Bingöl

1200, Turkey^1

Bitlis Eren University, Bitlis

13000, Turkey^2

Giresun University, Giresun

28100, Turkey^3

Afyonkocatepe University, Afyonkarahisar

03200, Turkey^4

关键词: Chemical parameters;    Effective atomic number;    Electronic cross sections;    Electrophilicity;    Indium complexes;    Mass attenuation coefficients;    Theoretical calculations;    Transmission geometries;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/707/1/012001/pdf
DOI  :  10.1088/1742-6596/707/1/012001

来源: IOP

【 摘 要 】

In this work, the mass attenuation coefficients, molecular, atomic and electronic cross sections, effective atomic numbers and electron densities of some selected indium complexes such as C5H10InNO9, C3H6InNO9and C9H10InNO9, were determined with experimentally and theoretically using transmission geometry at 59.54 keV photon energy which emitted from241Am annular source. The results were compared with the theoretical calculations which obtained from the WinXCOM program. Also, the results were interpreted based on some chemical parameters such as energy gap, ionization energy, electron affinity, hardness, chemical potential, electronegativity and global electrophilicity values of malonate, 2, 2 dimethylmalonate and phenylmalonate which were calculated using the density functional theory (DFT/B3LYP).