Highly Methanol Tolerant Cathode Based on PtAg for Use in Microfluidic Fuel Cell

15th International Conference on Micro and Nanotechnology for Power Generation and Energy Conversion Applications

物理学;能源学

Abrego-Martínez, J.C.^1 ; Mendoza-Huizar, L.H.^2 ; Ledesma-Garcia, J.^3 ; Arriaga, L.G.^1 ; Cuevas-Muñiz, F.M.^1

Centro de Investigación y Desarrollo Tecnólogico en Electroquímica, Parque Tecnológico Querétaro S/N, Pedro-Escobedo-Querétaro

76703, Mexico^1

Área Académica de Química, Universidad Autónoma Del Estado de Hidalgo, Carretera Pachuca-Tulancingo Km 4.5, Hidalgo-Mineral-de-la-Reforma

42184, Mexico^2

División de Investigación y Posgrado, Facultad de Ingeniería, Universidad Autónoma de Querétaro, Cerro de las campanas S/N, Santiago-de-Querétaro

76010, Mexico^3

关键词: Average diameter;    Bimetallic nanoparticles;    Electrochemical techniques;    Glassy carbon electrodes;    Methanol tolerant;    Microfluidic fuel cell;    Oxygen reduction reaction;    Voltammetric techniques;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/660/1/012079/pdf
DOI  :  10.1088/1742-6596/660/1/012079

来源: IOP

【 摘 要 】

In the present work, a methanol tolerant cathode catalyst was developed through the electrodeposition of bimetallic nanoparticles PtAg on a glassy carbon electrode using potentiostatic and voltammetric techniques. The resulting particles were characterized by Scanning Electron Microscopy (SEM) and electrochemical techniques. According to the SEM study the synthetized nanoparticles have semi-spherical shape and their average diameter is 100 nm. This material shows catalytic activity to the oxygen reduction reaction with high tolerance to methanol.