Layer-by-layer fully printed Zn-MnO2 batteries with improved internal resistance and cycle life

15th International Conference on Micro and Nanotechnology for Power Generation and Energy Conversion Applications

物理学;能源学

Kim, B.^1 ; Winslow, R.^1 ; Lin, I.^2 ; Gururangan, K.^2 ; Evans, J.^2 ; Wright, P.^1

Department of Mechanical Engineering, University of California, Berkeley

CA

94720, United States^1

Department of Materials Science and Engineering, University of California, Berkeley

CA

94720, United States^2

关键词: Catastrophic failures;    Cell discharge capacity;    Discharge capacities;    Functional cells;    Gel polymer electrolytes;    Internal resistance;    Polymer binders;    Specific energy;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/660/1/012009/pdf
DOI  :  10.1088/1742-6596/660/1/012009

来源: IOP

【 摘 要 】

This research created direct layer-by-layer printed zinc-based secondary batteries with an ionic liquid-based gel polymer electrolyte to power micro- and meso-scale devices. The use of a gel polymer electrolyte composed of [BMIM][Otf] ionic liquid, ZnOtf salt, and PVDF-HFP polymer binder enabled direct layer-by-layer printing of functional cells. The effects of additive printing methods on cell discharge capacity, cycle life, and internal resistance are discussed. Fully printed cells have demonstrated average discharge capacities of 0.548 mAh/cm2, energy densities of 8.20 mWh/cm3, and specific energies of 2.46 mWh/g with some cells achieving over 1000 cycles without catastrophic failure. Layer-by-layer printed devices exhibited decreased DC internal resistance and longer cycle life over previous mechanically assembled cells.