Valence-shell Photoelectron Circular Dichroism (PECD) on Chiral Halogenated Molecules in the Gas Phase

29th International Conference on Photonic, Electronic, and Atomic Collisions

Tia, Maurice^1 ; Garcia, Gustavo^1 ; Nahon, Laurent^1 ; Powis, Ivan^2

Synchrotron SOLEIL, L'Orme des Merisiers, St. Aubin, B.P.48, vGif sur Yvette

91192, France^1

School of Chemistry, University of Nottingham, Nottingham

NG7 2RD, United Kingdom^2

关键词: Chiral centers;    Chiral molecule;    Gasphase;    Valence shells;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/635/11/112011/pdf
DOI  :  10.1088/1742-6596/635/11/112011

来源: IOP

【 摘 要 】

We measured and calculated the PECD of three different halogenated chiral molecules in order to study the role of the localization of the initial orbital of the outgoing electron with respect to the chiral center.