Dynamics of dissociation in inner-valence excited 1,3-trans-Butadiene probed by 3-D multiple ion momentum imaging

29th International Conference on Photonic, Electronic, and Atomic Collisions

Oghbaie, S.^1 ; Gisselbrecht, M.^1 ; Sankari, A.^1 ; Mansson, E.^1 ; Laksman, J.^1 ; Sorensen, S.L.^1

Department of Physics, Lund University, Lund

S-221 00, Sweden^1

关键词: Ab initio calculations;    Ion momentum;    Nuclear dynamics;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/635/11/112009/pdf
DOI  :  10.1088/1742-6596/635/11/112009

来源: IOP

【 摘 要 】

The study focuses on rapid nuclear rearrangement/isomerization taking place in an early stage of butadiene fragmentation using multiple ion momentum imaging spectroscopy and tunable synchrotron radiation. In addition, ab initio calculations are performed to disentangle the nuclear dynamics preceding dissociation.