Interaction of the Mu-cyclohexadienyl radical with metallic (Au, Pt) nanoparticles in mesoporous silica

13th International Conference on Muon Spin Rotation, Relaxation and Resonance

Xiao, J.^1,2 ; Arseneau, D.J.^2 ; Bridges, M.D.^3 ; Cortie, D.^1,2,4 ; Cottrell, S.P.^5 ; Dehn, M.^6 ; Fleming, D.G.^1,2 ; Kelly, J.^1 ; Kiefl, R.F.^2,4 ; Macfarlane, W.A.^1,2,4 ; Maclachlan, M.^1 ; McKenzie, I.^2

Department of Chemistry, University of British Columbia, Vancouver

BC

V6T 1Z1, Canada^1

TRIUMF CMMS, 4004 Wesbrook Mall, Vancouver

BC

V6T 2A3, Canada^2

Department of Chemistry and Biochemistry, California State University, Fullerton

CA

92831, United States^3

Department of Physics and Astronomy, University of British Columbia, Vancouver

BC

V6T 1Z1, Canada^4

Rutherford Appleton Laboratory, Swindon

SN2 1SZ, United Kingdom^5

Physik-Department, Technische Universität München, James-Franck-Strasse 1, Garching bei München

85748, Germany^6

关键词: Isotropic hyperfine coupling constant;    Mesoporous Silica;    Metallic surface;    Structure and dynamics;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/551/1/012044/pdf
DOI  :  10.1088/1742-6596/551/1/012044

来源: IOP

【 摘 要 】

μSR and ALCR techniques have been used to investigate the structure and dynamics of the Mu-cyclohexadienyl radical interacting with Au and Pt metal nanoparticles (MNPs) supported in mesoporous silica (SBA-15). Surprisingly, coherent precession signals are observed and the isotropic hyperfine coupling constants are almost the same in loaded and unloaded samples, implying that the electronic structure of MuC6H6 is only weakly perturbed by the presence of the MNPs. We propose the observed radicals are shielded from the metallic surfaces by a benzene coating on the MNPs. The Δ1 resonance is observable in MNP-loaded samples at higher temperatures than in the unloaded SBA-15. This is attributed to stronger binding of MuC6H6 to the benzene coated MNPs.