Rapid bond rearrangement in molecules after core-electron excitation

28th International Conference on Photonic, Electronic and Atomic Collisions

Sorensen, S.L.^1 ; Gisselbrecht, M.^1 ; Laksman, J.^1,3 ; Månsson, E.P.^1 ; Céolin, D.^1,4 ; Sankari, A.^1 ; Afaneh, F.^2

Department of Physics, Lund University, Box 118, Lund

22100, Sweden^1

Hashemite University, Box 150459, Zarqa, Amman

13115, Jordan^2

MAX-Lab, Lund University, Box 118, Lund

221 00, Sweden^3

Synchrotron SOLEIL, L'Orme des Merisiers, St. Aubin BP 48, Gif-sur-Yvette

F-91192, France^4

关键词: Bond rearrangement;    Carbonyl sulphides;    Core electron excitations;    Core-excited molecules;    Core-excited state;    Fragmentation channels;    Molecular dissociation;    Molecular geometries;   

Others  :  https://iopscience.iop.org/article/10.1088/1742-6596/488/1/012006/pdf
DOI  :  10.1088/1742-6596/488/1/012006

来源: IOP

【 摘 要 】

Experimental studies of core-excited molecules using three-dimensional multi particle momentum imaging are presented where bond rearrangement processes in dication species are analysed. The aim of the study is to understand the relation between the geometric changes associated with core-excited states and the kinetic energy released in particular molecular dissociation processes. The kinematics of individual fragmentation channels are studied by fully three-dimensional momentum imaging of fragments in coincidence. Examples are presented where the high efficiency of the instrument and the fully three-dimensional momentum capabilities are exploited to understand nuclear motion leading to bond rearrangement in core-excited states. We identify bond-rearrangement processes in water, carbonyl sulphide and acetylene which are initiated in the core-excited state. In water this is evidenced by the H+2/O+ion pair, and in carbonyl sulphide the OS++C+pair is the fingerprint of this reaction. In acetylene the H+2+ C+2ion pair indicates a molecular geometry that changes from linear to strongly bent. We measure the angular distribution of all fragments and fragment pairs and for the bond rearrangement processes in water and in core-excited acetylene the angular distribution of fragments suggests that the bond rearrangement is very rapid.