Preparation and Characterization of Ce-Zr/Al-MCM-41 Bimetallic Catalyst for Transesterification of Jatropha Oil to Biodiesel

2018 4th International Conference on Renewable Energy Technologies

Jibril, Z.I.^1 ; Ramli, A.^1 ; Jumbri, K.^1

Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Malaysia^1

关键词: Analytical method;    Bimetallic catalysts;    Catalyst loadings;    Coimpregnation;    Fatty acid methyl ester;    Heterogeneous catalyst;    N2 adsorption;    Stability of structures;   

Others  :  https://iopscience.iop.org/article/10.1088/1755-1315/168/1/012013/pdf
DOI  :  10.1088/1755-1315/168/1/012013

来源: IOP

【 摘 要 】

A series of bimetallic Ce-Zr heterogeneous catalysts supported on Al-MCM-41 aluminosilicate with cerium and zirconium loading ranging from 2.5 to 7.5 wt%, were prepared by co-impregnation method. The characterization of the catalysts obtained by various analytical methods; XRD, N2 adsorption-desorption, FESEM, EDX and TPD NH3. The result shows that metals were well incorporated in the framework of the support, catalysts retained the mesoporous character and stability of structure after impregnation. The catalysts were active in one step transesterification of non-edible jatropha oil to produce fatty acid methyl esters (FAME) with methanol to oil ratio 6:1 at 90C, after 4 h reaction time. The FAME yield was found to have the maximum activity, higher than 80% with catalyst 5 wt% Ce and 5 wt% Zr loadings supported by Al-MCM-41 with catalyst loading 5 wt%. The catalyst was recovered by simple filtration.