Direct Solvothermal Liquefaction of Pennisetum purpureum Biomass to Produce Biocrude Using Ethanol Solvent

2017 International Conference on Renewable Energy and Environment

能源学;生态环境科学

Ochiai, Mikael Adriane^1 ; Cruz, Salvador Marrod^1 ; Oporto, Louiellyn^1 ; De Leon, Rizalinda^1

Department of Chemical Engineering, University of the Philippines Diliman, Quezon City, Philippines^1

关键词: Crude products;    Deoxygenations;    Effects of temperature;    High temperature;    Higher heating value;    Interaction effect;    Lignocellulosic biomass;    Pennisetum purpureum;   

Others  :  https://iopscience.iop.org/article/10.1088/1755-1315/127/1/012006/pdf
DOI  :  10.1088/1755-1315/127/1/012006

学科分类：环境科学（综合）

来源: IOP

【 摘 要 】

Direct solvothermal liquefaction was used in converting the lignocellulosic biomass, Pennisetum purpureum or Napier grass using ethanol as solvent. Liquefaction of Napier grass resulted in a dark and viscous bio-crude product and exhibited promising yields (34.6377% to 48.6267%). It was determined that the effects of temperature and residence time were statistically significant with the residence time having the greatest positive effect on yield. High yields of bio-crude from Napier grass seem to occur when solvothermal temperature, residence time increased and as solids ratio decreased. However, elemental analysis showed that the bio-crude produced needs to undergo deoxygenation (O: 14.25 - 49.42%) before mixing with petroleum. For the higher heating value (HHV), the parameters observed in the study were statistically insignificant, however, temperature was determined to have the greatest positive effect on HHV. It was observed that high HHV bio-crude were produced at high temperatures, low solids ratio, and low residence times. The acquired averages for the HHV (20.0333 MJ/kg to 29.7744 MJ/kg) were all higher than the HHV of the Napier grass sample used in the study (12.9394 MJ/kg). It was observed in the study, that even though solids ratio has the least effect on both responses, the choice of solids ratio is dependent on its interaction effects with the other parameters as its effects contribute to the observed responses.