Utilization of sulphurized palm oil as cutting fluid base oil for broaching process

1st International Symposium on Green Technology for Value Chains 2016

工业技术;生态环境科学

Sukirno^1 ; Ningsih, Y.R.^1

Department of Chemical Engineering, University of Indonesia, Depok, Indonesia^1

关键词: Environmental issues;    Extreme pressure additives;    Industrial cutting fluids;    Metal-to-metal contact;    Optimum formulation;    Oxidative stability;    Performance parameters;    Sulphur containing compounds;   

Others  :  https://iopscience.iop.org/article/10.1088/1755-1315/60/1/012008/pdf
DOI  :  10.1088/1755-1315/60/1/012008

来源: IOP

【 摘 要 】

Broaching is one of the most severe metal cutting operation that requires the use of cutting fluids formulated with extreme pressure (EP) additives to minimize metal-to-metal contact and improve tool life. Enhancement of EP performances of the cutting fluids can be achieved by addition of sulphur containing compounds that will allow the formation of metal sulfide film that has low shear strength and good antiweld properties and acts as protection layer from wear and seizure. Most of the cutting fluids are mineral oil based. However, as regards to health and environmental issues, reseach on vegetable oil based cutting fluid have been increased recently. This paper reports a study on the sulphurization of palm oil derivatives and its usage as broaching oil. Sulphurization of the palm oil derivative was conducted via non-catalytic sulphurization using elemental sulphur at various composition and under heating of 150-160°C for 3 hr. Broaching oil was made by blending the sulphurized palm oil and additive packages. The performance parameters of the broaching oil that has been observed including load carrying capacity, wear scar diameter, corrosion protection, oxidative stability, and surface finish of workpiece. From this research, it was found that sulphurized FAME based broaching oil has excellent EP properties. The optimum formulation was obtained on composition of sulphurized FAME-mineral oil with 6% wt of sulphur. The result from the test showed that kinematic viscosity of sulphurized palm oil was about 25.3 cSt (at 40 °C), load carrying capacity was 400 kgf, and wear scar diameter was 0.407 mm. In addition, it can be concluded that the class of corrosion protection of modified palm oil was 1.b (slight tarnish category), oxidative stability at 160 °C was obtained for 0.11 hr, and the surface roughness of workpiece was about 0.0418-0.0579 μm. These performances are comparable to commercial broaching oil. By this result, it indicates that sulphurized palm oil is applicable for industrial cutting fluids formulation.