Preparation and characterization of Polyacrylonitrile/ Manganese Dioxides- based Carbon Nanofibers via electrospinning process

International Conference on Chemical and Bioprocess Engineering

地球科学;化学;生物科学

Othman, F.E. Che^1,2 ; Yusof, N.^1,2 ; Jaafar, J.^1,2 ; Ismail, A.F.^1,2 ; Hasbullah, H.^1,2 ; Abdullah, N.^1,2 ; Ismail, M.S.^1,2

Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, Skudai, Johor Bahru

81310, Malaysia^1

Faculty of Petroleum and Renewable Energy Engineering (FPREE), Universiti Teknologi Malaysia, Skudai, Johor Bahru

81310, Malaysia^2

关键词: Carbonization process;    Carbonization temperatures;    Electrospinning method;    Electrospinning process;    Micro-structural properties;    N ,N-Dimethylformamide;    Polyacrylonitrile (PAN);    Stabilization temperatures;   

Others  :  https://iopscience.iop.org/article/10.1088/1755-1315/36/1/012006/pdf
DOI  :  10.1088/1755-1315/36/1/012006

学科分类：生物科学（综合）

来源: IOP

【 摘 要 】

This research reports the production of precursor polyacrylonitrile (PAN)/ manganese dioxide (MnO2) nanofibers (NFs) via electrospinning method followed by stabilization and carbonization processes. Nowadays, electrospinning has become a suitable method in manufacturing continuous NFs, thus it is employed to fabricate NFs in this study. The microstructural properties and adsorption competencies of the produced NFs were also studied. The NFs were prepared by electrospinning the polymer solution of Polyacrylonitrile (PAN) and Manganese Dioxide (MnO2) in, N, N-Dimethylformamide (DMF) solvent. The factors considered in this study were various polymer PAN/MnO2concentrations which will significantly affect the specific surface area, fiber morphology and the diameter of the NFs prepared. Subsequently, heat treatment is applied by setting up the stabilization temperature at 275 °C and carbonization temperature at 800 °C with constant dwelling time (30 min). Nitrogen gas at constant rate 0.2 L/min was used for stabilization and carbonization with the stabilization rate (2 °C/min) and carbonization rate (5 °C/min). The carbon nanofibers (CNFs) produced were characterized using Scanning Electron Microscopy (SEM), Brunauer Emmett and Teller (BET) surface area and Fourier Transmission Infrared Spectroscopy (FTIR). It was found that the PAN/MnO2CNFs were successfully produced with the carbonization temperature of 800 °C. The prepared PAN/MnO2CNFs prepared showed an enhanced in specific surface area about two times compared to it precursor NFs.