Study on novel structure of 4-amino-2-chloropyridine bis(salicylato)borate hydrate

3rd International Symposium on Resource Exploration and Environmental Science

生态环境科学

Yan, Yongmei^1 ; Liu, Haixing^1 ; Wang, Lintong^1

College of Chemistry and Chemical Engineering, Weifang University, Weifang

261061, China^1

关键词: 4-amino-2-chloropyridine bis(salicylato)borate;    B atoms;    Borate hydrates;    Hydrogen bonding interactions;    Hydrothermal reaction;    Novel structures;    Single crystal x-ray diffraction;    Structure analysis;   

Others  :  https://iopscience.iop.org/article/10.1088/1755-1315/300/5/052004/pdf
DOI  :  10.1088/1755-1315/300/5/052004

学科分类：环境科学（综合）

来源: IOP

【 摘 要 】

A novel complex C14H8BO6. (C5H6ClN2). (H2O) has been synthesized from a hydrothermal reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction. Orthorhombic, Pccn. a=16.6736(13) Å, b=29.447(3) Å, c=8.1366(6) Å, α=β=γ=90°. V=3995.0(6) Å3. Z=8. R1 = 0.0567, wR2 = 0.1624, T=293(2)K. The B atom is coordinated by four O atoms from two salicylic acid molecular. The molecular structure stabilized by the O-H...O and O-H...N hydrogen-bonding interactions.