Preparation and properties of Sulfur/Mesoporous Carbon Composite Cathode Materials

2018 4th International Conference on Environmental Science and Material Application

生态环境科学;材料科学

Zhang, Wenhua^1^3 ; Liu, Ping^2 ; Liu, Jia^1 ; Dai, Xiaoming^2 ; Wu, Fayuan^2

Nanchang Institute of Technology, Nanchang, China^1

State Grid of Jiangxi Electric Power Research Institute, Nanchang, China^2

Nanchang Institute of Technology, Jiangxi Province Key Laboratory of Precision Drive and Control, Nanchang, China^3

关键词: Cath-ode materials;    Electrochemical activities;    Electrochemical performance;    Galvanostatic methods;    High current densities;    Organic electrolyte;    Rate capabilities;    Specific capacities;   

Others  :  https://iopscience.iop.org/article/10.1088/1755-1315/252/2/022067/pdf
DOI  :  10.1088/1755-1315/252/2/022067

来源: IOP

【 摘 要 】

A sulfur / mesoporous carbon composite is prepared by thermally treating a mixture of sublimed sulfur and mesoporous carbon. The microstructure of the mesoporous carbon is characterized by BET analysis and X-ray diffraction (XRD). The electrochemical performance of the S / C composite as cathode materials is evaluated by the galvanostatic method. The results confirmed that the mesoporous carbon could not only greatly enhance the electrochemical activity of sulfur electrode, but also effectively confine the diffusion of dissolved polysulfides in organic electrolyte. As a result, the S / C composites showed high capacity, good cycle performance and excellent rate capability. The specific capacity of the S / C composite is more than 1200 mAh / g for the first discharge, and remained at 800 mAh / g after 100 cycles even at a high current density of 800 mA/g.