会议论文详细信息
2018 4th International Conference on Environmental Science and Material Application
Synthesis and Structural Characterization of a Ni(II) Coordination Polymer Based on 4,4'-Bipyridine and Acetato
生态环境科学;材料科学
Wang, Lihua^1 ; Lin, Dandan^2 ; Liang, Qian^2
College of Information and Control Engineering, Weifang University, Weifang
261061, China^1
College of Chemistry and Chemical Engineering, Weifang University, Weifang
261061, China^2
关键词: Bipyridines;    Coordination Polymers;    Layered Structures;    Ni complexes;    Octahedral geometry;    Space Groups;    Structural characterization;    X-ray single crystal;   
Others  :  https://iopscience.iop.org/article/10.1088/1755-1315/252/2/022025/pdf
DOI  :  10.1088/1755-1315/252/2/022025
来源: IOP
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【 摘 要 】

A new coordination polymer, [Ni(bpy)(acetato)2]n (bpy = 4,4'-bipyridine), was synthesized and characterized by X-ray single-crystal structural analysis. For the complex: C14H14N2NiO4, M r = 332.98, triclinic, space group P-1, a = 8.0538(16) Å, b = 9.1680(18) Å, c = 10.659(2) Å, α = 109.80(3)°, β = 99.90(3)°, γ = 101.81(3)°, V= 699.5(2) Å3, Z = 2, Dc = 1.581g•cm-3, μ = 1.403mm-1, F(000) = 344, and final R 1 = 0.0603, ωR 2 = 0.1730. The Ni(II) ion adopts a distorted octahedral geometry coordinated by two N atoms and four O atoms. The Ni(II) complex forms 1D chain structure 2D layered structure by the bridge of 4,4'-bipyridine and acetato.

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