Simulation of the Reactivity of Energy Materials in the Technosphere

All-Russian research-to-practice conference "Ecology and safety in the technosphere: current problems and solutions"

工业技术（总论）

Rodzevich, A.P.^1 ; Kuzmina, L.V.^2 ; Gazenaur, E.G.^2 ; Krasheninin, V.I.^2

Yurga Institute of Technology (Affiliate), Tomsk Polytechnic University, 26 Leningradskaya Street, Yurga

652050, Russia^1

Kemerovo State University, 6 Krasnaya Street, Kemerovo

650000, Russia^2

关键词: Chemical process;    Loss of performance;    Mechanical action;    Mechanical effects;    Mechanical stress;    Negative temperatures;    Storage temperatures;    Useful properties;   

Others  :  https://iopscience.iop.org/article/10.1088/1755-1315/224/1/012018/pdf
DOI  :  10.1088/1755-1315/224/1/012018

学科分类：工业工程学

来源: IOP

【 摘 要 】

Methods are proposed for regulating the reactivity of energetic materials that circulate in the technosphere and are not rarely the cause of fires and explosions, both during storage and during transportation. As man-made factors that influence the stability of these materials magnetic and temperature fields and mechanical effects were used. The magnetic field (in the range from 0.01 T to 0.3 T) was used to intensify chemical processes, both at the stage of crystal growth (by the example of silver azide) and together with mechanical action (from 105 Pa to 107 Pa) in the finished crystals. The action of the magnetic field and mechanical stress leads to the stimulation of microplasticity and macroplasticity processes, which are accompanied by a slow decomposition of the samples and subsequent destruction. It was established experimentally that a slight change in storage temperature, as compared to room temperature, accelerates the aging process of samples (range of positive temperatures up to + 30°C), or leads to loss of plasticity (range of negative temperatures down to -20°C) resulting in loss of performance and in loss of useful properties of energy materials.