Effect of Temperature Synthesis on Structural Behaviours of NaY Zeolite Using Local Sand as A Silica Source

International Conference on Condensed Matters and Advanced Materials 2018

Sumari, Sumari^1 ; Fajaroh, Fauziatul^1 ; Yahmin^1 ; Sholihah, Ni'Matus^1 ; Santoso, Aman^1 ; Budianto, Agus^2

Chemistry Department, Faculty of Mathematics and Science, State University of Malang, Jl. Semarang No.5, Malang

65145, Indonesia^1

Chemical Engineering Department, Faculty of Technology, Surabaya Institute of Adhi Tama Technology, Jalan Arief Rachman Hakim No. 100, Surabaya

60117, Indonesia^2

关键词: Crystallization temperature;    Diffractograms;    Effect of temperature;    NaY zeolite;    Silica sources;    Structural behaviour;    Surface area;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/515/1/012036/pdf
DOI  :  10.1088/1757-899X/515/1/012036

来源: IOP

【 摘 要 】

The purpose of this study was to synthesize NaY zeolite by utilizing local sand as a source of silica which was carried out at various crystallization temperatures. The synthesis of NaY zeolite is carried out using silica resulted from the purification of local sand while NaOH and Al2O3 are pure analysis (pa) quality. Crystallization temperature was carried out at various temperatures of 80, 100, and 150 °C. The synthesis results were characterized by physical properties, XRF, FTIR, XRD, SEM, surface area. NaY zeolite was successfully synthesized supported by FTIR data by the presence of functional groups such as Si-O, O-Al-O, Si-OH, and O-H from Si-OH, and SEM data which showed the formation of cube-shaped crystals. The formation of NaY zeolite is also strengthened by the appearance of peaks with a sharp intensity from XRD diffractogram that this zeolite is NaY and as well as data molar ratio of Si/Al is in the range of 2.027 to 2.045 respectively at various crystallization temperature. The crystallization temperature of 80 °C produces NaY zeolite better than that of crystallization temperatures of 100 and 150 °C. The synthesized NaY zeolites using local sand have a good surface area that is 658 m2/g. The crystallization temperature affects the success of NaY zeolite synthesis.